Stereoselective synthesis of α-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids

被引：75
|
作者：
Miura, Tomoya
Shimada, Masahiko
Ku, Sung-Yu
Tamai, Tomohiro
Murakami, Masahiro
机构：
[1] Kyoto Univ, Dept Synth Chem & Biolog Chem, Kyoto 6159510, Japan
[2] Natl Taiwan Univ, Dept Chem, Taipei, Taiwan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 37期
关键词：
beta-oxygen elimination; addition; allenes; boron; rhodium;
D O I：
10.1002/anie.200701505
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Better than Cu, Pd, and Fe catalysts: The rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids provides synconfigured α-allenols with excellent diastereoselectivity. Precoordination of the oxygen atom of the oxirane ring to rhodium is assumed to contribute to the high stereoselectivity as well as high reactivity. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7101 / 7103
页数：3
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