Rhodium-catalyzed arylative cyclization of alkynones induced by addition of arylboronic acids

被引：38
|
作者：
Miura, Tomoya [1 ]
Shimada, Masahiko [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan
来源：
TETRAHEDRON | 2007年 / 63卷 / 27期
基金：
日本学术振兴会;
关键词：
D O I：
10.1016/j.tet.2007.03.025
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkynones react with arylboronic acids in the presence of a rhodium(I) catalyst to afford four- and five-membered-ring cyclic alcohols equipped with a tetrasubstituted exocyclic olefin. The cyclic allylic alcohol skeleton is constructed by the carbon-carbon bond formation between the carbonyl group and an alkenylrhodium(I) intermediate formed by the regioselective addition of an arylrhodium(I) species across the carbon-carbon triple bond. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6131 / 6140
页数：10
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