Shale gas;
Ethylene;
Oxidative coupling of methane;
Methanol to olefins;
Techno-economic analysis;
CO2-emissionsa;
UOP/HYDRO MTO PROCESS;
NATURAL-GAS;
OPERATING-CONDITIONS;
METHANE;
PROPYLENE;
ALTERNATIVES;
INTEGRATION;
REACTORS;
D O I:
10.1016/j.compchemeng.2017.05.023
中图分类号:
TP39 [计算机的应用];
学科分类号:
081203 ;
0835 ;
摘要:
Shale gas is being considered as feedstock for the production of major petrochemicals. One such chemical is ethylene. Although the typical production for ethylene is carried out via thermal cracking, alternative processes have been gaining importance recently. Among such alternatives are the Oxidative Coupling of Methane (OCM) and the Methanol to Olefins (MTO) processes. The first one is a direct conversion process while the second one involves several stages. The aim of this work is to carry out an economic, energy and environmental assessment for these two processes. The results show that the MTO process is more profitable under the economic and technical scenario considered here. A sensitivity analysis was conducted to show the shale gas and ethylene prices under which the OCM process would be economically attractive. An analysis on catalyst improvement needed for the OCM process to be profitable is also reported. (C) 2017 Elsevier Ltd. All rights reserved.
机构:
Iowa State Univ, Bioecon Inst, Biorenewable Res Lab 3116, Ames, IA 50011 USAIowa State Univ, Bioecon Inst, Biorenewable Res Lab 3116, Ames, IA 50011 USA
Brown, Tristan R.
Wright, Mark M.
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机构:
Iowa State Univ, Dept Mech Engn, Ames, IA 50011 USAIowa State Univ, Bioecon Inst, Biorenewable Res Lab 3116, Ames, IA 50011 USA
机构:
South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R ChinaSouth China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
Yang, Qingchun
Qian, Yu
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South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R ChinaSouth China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
Qian, Yu
Zhou, Huairong
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South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R ChinaSouth China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
Zhou, Huairong
Yang, Siyu
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机构:
South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R ChinaSouth China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
机构:
Fraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
Karlsruhe Inst Technol KIT, Hermann Von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, GermanyFraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
Semmel, Malte
Kerschbaum, Maximilian
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Fraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, GermanyFraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
Kerschbaum, Maximilian
Steinbach, Benedikt
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Fraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, GermanyFraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
Steinbach, Benedikt
Sauer, Joerg
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Karlsruhe Inst Technol KIT, Hermann Von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, GermanyFraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
Sauer, Joerg
Salem, Ouda
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Fraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, GermanyFraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
机构:
Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
Chongqing Univ Sci & Technol, Sch Petr Engn, Chongqing 401331, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
Liang, Hong-Bin
Zhang, Lie-Hui
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Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
Zhang, Lie-Hui
Zhao, Yu-Long
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机构:
Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
Zhao, Yu-Long
He, Xiao
论文数: 0引用数: 0
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机构:
PetroChina Southwest Oil & Gasfield Co, Chengdu 610500, Sichuan, Peoples R China
Sichuan Changning Nat Gas Dev Co Ltd, Chengdu 610500, Sichuan, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
He, Xiao
Wu, Jian-Fa
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机构:
Sichuan Changning Nat Gas Dev Co Ltd, Chengdu 610500, Sichuan, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
Wu, Jian-Fa
Zhang, Jing
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机构:
Sichuan Changning Nat Gas Dev Co Ltd, Chengdu 610500, Sichuan, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China
Zhang, Jing
Yang, Jun
论文数: 0引用数: 0
h-index: 0
机构:
PetroChina Southwest Oil & Gasfield Co, Chengdu 610500, Sichuan, Peoples R ChinaSouthwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Sichuan, Peoples R China