trans-Di-μ-chloro-bis[chloro(triphenylphosphine)palladium] benzene disolvate

被引：9
|
作者：
Sui-Seng, C [1 ]
Bélanger-Gariépy, F [1 ]
Zargarian, D [1 ]
机构：
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803015502
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, trans-[PdCl2(PPh3)](2), in the crystal structure of its benzene disolvate, [Pd2Cl4(C18H15P)(2)].-2C(6)H(6),occupies a special position in the inversion centre. The Pd atom has a distorted square-planar coordination environment formed by a triphenylphosphine [Pd-P 2.2278 (6) Angstrom], a terminal chloride [Pd-Cl 2.2722 (7) Angstrom], and two bridging chloride ligands. The Pd-mu-Cl bond in the transposition to the phosphine ligand [2.4128 (6) Angstrom] is considerably longer than the Pd-mu-Cl bond in the trans- position to the terminal chloride [2.3228 (6) Angstrom].
引用
收藏
页码：M618 / M619
页数：2
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