Chloro(triphenylphosphine)(tropolonato)palladium(II)

被引：3

作者：

Steyl, G ^{[1
]}

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806011652

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Pd(C7H5O2)Cl(C18H15P)], is a new type of alpha-diketone palladium(II) complex containing a tertiary arylphosphine. It crystallizes with a distorted square-planar geometry about the palladium( II) metal centre. The most important bond distances and angles include Pd-O (trans P) = 2.0481 (12) angstrom, Pd-O (trans Cl) = 2.0016 (12) angstrom, Pd-P = 2.2268 (4) angstrom, Pd-Cl = 2.2770 (5) angstrom, O-Pd-O = 80.22 (5)degrees and O-C-C-O = 3.7 (2)degrees. A pi-pi stacking interaction is observed between neighbouring tropolonate groups, with an interplanar distance of 3.377 (6) angstrom.

引用

页码：M974 / M976

页数：3

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