Di-μ-phenylselenolato-bis[chloro(triphenylphosphine)palladium(II)]

被引：3
|
作者：
Hannu-Kuure, MS
Oilunkaniemi, R
Laitinen, RS
Ahlgren, M
机构：
[1] Univ Oulu, Dept Chem, FIN-90014 Oulu, Finland
[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804000960
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Pd2Cl2(mu-C6H5Se)(2)(C18H15P)(2)], crystallizes as a centrosymmetric phenylselenolato-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with the Pd-Se distance trans to the terminal Cl- ligand at 2.4174 (6) Angstrom and that trans to the triphenyl phospine at 2.4748 (7) Angstrom. These values are consistent with the relative trans influence of Cl- and PPh3. The terminal Cl- ligands are in trans positions with respect to each other.
引用
收藏
页码：M214 / M216
页数：3
相关论文
共 50 条
  • [1] trans-Di-μ-chloro-bis[chloro(triphenylphosphine)palladium] benzene disolvate
    Sui-Seng, C
    Bélanger-Gariépy, F
    Zargarian, D
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M618 - M619
  • [2] trans-Chloro(methyl)bis(triphenylphosphine)-palladium(II)
    Otto, S
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : m75 - m77
  • [3] Di-μ-pyridine-2-thiolato-bis[chloro(triphenylphosphine)copper(I)]
    Marjani, K
    Davies, SC
    Durrant, MC
    Hughes, DL
    Khodamorad, N
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M744 - M746
  • [4] Di-μ-furan-2-selenolato-bis[(furan-2-selenolato)-(triphenylphosphine) palladium(II)]
    Wagner, A
    Hannu-Kuure, MS
    Oilunkaniemi, R
    Laitinen, RS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2198 - M2200
  • [5] Inhibition of a palladium(II) catalyst upon formation of a di-μ-chloro complex:: di-μ-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P′]-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate
    Abu-Surrah, AS
    Klinga, M
    Repo, T
    Leskelä, M
    Debaerdemaeker, T
    Rieger, B
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : E44 - E45
  • [6] Di-μ-chloro-bis[chloro(tricyclohexylphosphine-κP)mercury(II)]
    Liu, LH
    Zhang, QF
    Leung, WH
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M394 - M395
  • [7] Syntheses and crystal structures of di-μ-chloro-bis [dithiocyanatoselenate(II)] and di-μ-bromo-bis [dithiocyanatoselenate(II)] salts
    Eriksen, K
    Hauge, S
    Maroy, K
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 174 : 209 - 221
  • [8] Di-μ2-chloro-bis[(benzyldiphenylphosphine)chloropalladium(II)]
    Meijboom, R
    Muller, A
    Roodt, A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M897 - M899
  • [9] Di-μ-chloro-bis[aqua(caffeine)chlorocopper(II)]
    Jin, ZM
    Feng, WJ
    Li, L
    Ma, XJ
    Deng, DS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2631 - M2633
  • [10] Two phases of bis(tetraethylammonium) di-μ-chloro-bis[dichloropalladium(II)]
    Fábry, J
    Dusek, M
    Fejfarová, K
    Krupková, R
    Vanek, H
    Nemec, I
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2004, 60 (09) : M426 - M430
12345