Di-μ-phenylselenolato-bis[chloro(triphenylphosphine)palladium(II)]

被引：3
|
作者：
Hannu-Kuure, MS
Oilunkaniemi, R
Laitinen, RS
Ahlgren, M
机构：
[1] Univ Oulu, Dept Chem, FIN-90014 Oulu, Finland
[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804000960
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Pd2Cl2(mu-C6H5Se)(2)(C18H15P)(2)], crystallizes as a centrosymmetric phenylselenolato-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with the Pd-Se distance trans to the terminal Cl- ligand at 2.4174 (6) Angstrom and that trans to the triphenyl phospine at 2.4748 (7) Angstrom. These values are consistent with the relative trans influence of Cl- and PPh3. The terminal Cl- ligands are in trans positions with respect to each other.
引用
收藏
页码：M214 / M216
页数：3
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