A novel comparative photothermal method for measuring thermal diffusivity

A novel comparative method has been developed at the National Physical Laboratory (NPL) to measure the thermal diffusivity of semi-infinite samples without a priori knowledge of the boundary conditions. It is based on photothermal radiometry, and involves the detection of modulated thermal radiance from a target irradiated by a modulated. focused diode laser beam with a power of 1 W. The technique exploits the fact that the frequency response of the surface temperature modulation scales with thermal diffusivity for a given target geometry (this is a fundamental property of the heat diffusion equation). In the process two samples are measured, one of which is known, and the diffusivity of the second material is derived from scaling the results over frequency. Measurements on samples of platinum and Inconel have shown the validity of the methodology but also raised issues concerning the difficulty of accurate measurements due to surface coatings or roughness.