A Zn(II) complex with a pyridyl-and carboxylate-containing ligand: synthesis and structural characterization

被引：2
|
作者：
Hu, Tao [1 ]
Zhu, Xiao-Hong [1 ]
Jiang, Ding-Yun [1 ]
Cheng, Xiao-Chun [1 ]
Kuai, Hai-Wei [1 ]
机构：
[1] Huaiyin Inst Technol, Fac Chem Engn, Huaian 223003, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2020年 / 75卷 / 04期
关键词：
crystal structure; fluorescence; N; O-functional ligand; Zn(II);
D O I：
10.1515/znb-2019-0225
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrothermal reaction of Zn(II) nitrate hydrate with 5-(pyridin-4-yl)isophthalic acid (H2L) yields the complex [Zn-2(L)(2)(H2O)(2)]center dot 2(H2O) (1), which has been characterized by single crystal X-ray diffraction, IR spectroscopic, elemental, and thermogravimetric analyses. Complex 1 exhibits a 3-nodal (3,6)-connected 2D net structure with (4.6(2))(2)(4(2).6(10).8(3))(6(3))(4) topology. Its luminescence property was investigated, but the results show that the coordination to the zinc atom has no significant effect on the emission of the ligand.
引用
收藏
页码：379 / 382
页数：4
相关论文
共 50 条
  • [1] Design and synthesis of a novel carboxylate-containing ligand
    Lajmi, AR
    Canary, JW
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 483 - INOR
  • [2] Synthesis of a homochiral carboxylate-containing tetradentate ligand and its Co(III) complex
    Lee, Seok Jong
    Sung, Hye Ran
    Son, Jeong-Ho
    Ramesh, Rengan
    Ahn, Kyo Han
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (05) : 518 - 521
  • [3] Synthesis, structure and property of lanthanide-organic frameworks with pyridyl- and carboxylate-containing ligand
    Chen, Man-Sheng
    Fan, Jian
    Okamura, Taka-aki
    Lv, Gao-Chao
    Sun, Wei-Yin
    [J]. INORGANICA CHIMICA ACTA, 2011, 366 (01) : 268 - 274
  • [4] Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate- and benzimidazolyl-containing ligand
    Dai, C. H.
    Mao, F. L.
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2015, 41 (06) : 405 - 409
  • [5] Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate- and benzimidazolyl-containing ligand
    C. H. Dai
    F. L. Mao
    [J]. Russian Journal of Coordination Chemistry, 2015, 41 : 405 - 409
  • [6] Synthesis, structural characterization and chromotropism of a copper(II) complex containing a bidentate ligand
    Golchoubian, Hamid
    Tarahomi, Mahbobeh
    Rezaee, Ehsan
    Bruno, Giuseppe
    [J]. POLYHEDRON, 2015, 85 : 635 - 642
  • [7] Structural variation in manganese complexes: Synthesis and characterization of manganese complexes from carboxylate-containing chelating ligands
    Iikura, H
    Nagata, T
    [J]. INORGANIC CHEMISTRY, 1998, 37 (18) : 4702 - 4711
  • [8] Synthesis and characterization of a ruthenocene carboxylate containing ruthenium(II) complex
    Wyman, IW
    Robertson, KN
    Cameron, TS
    Swarts, JC
    Aquino, MAS
    [J]. ORGANOMETALLICS, 2005, 24 (24) : 6055 - 6058
  • [9] A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
    Kuai, Hai-Wei
    Hu, Tao
    Jiang, Ding-Yun
    Zhu, Xiao-Hong
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2018, 73 (06): : 407 - 411
  • [10] Design and synthesis of a carboxylate-containing ligand that increases the T1-weighted relaxivity response of a manganese complex to hydrogen peroxide
    Hutchinson, Tessa
    Goldsmith, Christian
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
12345