Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate- and benzimidazolyl-containing ligand

被引：0
|
作者：
C. H. Dai
F. L. Mao
机构：
[1] Yancheng Teachers University,School of Chemistry and Chemical Engineering
来源：
Russian Journal of Coordination Chemistry | 2015年 / 41卷
关键词：
Benzoic Acid; Coordination Chemistry; Coordination Polymer; Benzimidazolyl; Isophthalic Acid;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The hydrothermal reaction of cadmium salt with 3,5-bis(benzimidazol-1-ylmethyl)benzoic acid (HL) forms a new complex [Cd(L)2] · 3H2O (I). This complex has been characterized by single-crystal X-ray diffraction, IR, elemental and thermogravimetric analyses and shows 3D flu framework structure with 2-nodal (3,6)-connected (42.6)2(44.62.89) topology. Luminescent property of I was investigated. Moreover, single crystals of HL were obtained accidentally in the hydrothermal reaction of the HL with MnSO4 at 160°C, and its crystal structure has been characterized by single-crystal X-ray diffraction (CIF files CCDC nos. 1020274 (HL) and 1020275 (I)).
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页码：405 / 409
页数：4
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