A Zn(II) complex with a pyridyl-and carboxylate-containing ligand: synthesis and structural characterization

被引：2
|
作者：
Hu, Tao [1 ]
Zhu, Xiao-Hong [1 ]
Jiang, Ding-Yun [1 ]
Cheng, Xiao-Chun [1 ]
Kuai, Hai-Wei [1 ]
机构：
[1] Huaiyin Inst Technol, Fac Chem Engn, Huaian 223003, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2020年 / 75卷 / 04期
关键词：
crystal structure; fluorescence; N; O-functional ligand; Zn(II);
D O I：
10.1515/znb-2019-0225
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrothermal reaction of Zn(II) nitrate hydrate with 5-(pyridin-4-yl)isophthalic acid (H2L) yields the complex [Zn-2(L)(2)(H2O)(2)]center dot 2(H2O) (1), which has been characterized by single crystal X-ray diffraction, IR spectroscopic, elemental, and thermogravimetric analyses. Complex 1 exhibits a 3-nodal (3,6)-connected 2D net structure with (4.6(2))(2)(4(2).6(10).8(3))(6(3))(4) topology. Its luminescence property was investigated, but the results show that the coordination to the zinc atom has no significant effect on the emission of the ligand.
引用
收藏
页码：379 / 382
页数：4
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