Preparation of optically active β-amino acids from microbial polyester polyhydroxyalkanoates

被引：0

作者：

Park, SH

Lee, SH

Lee, SY

机构：

[1] Korea Adv Inst Sci & Technol, Metab & Biomol Engn Natl Res Lab, Dept Chem Engn, Yusong Gu, Taejon 305701, South Korea

[2] ChiroBio Inc, Yusong Gu, Taejon 305301, South Korea

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2001年 / 11期

关键词：

optically active beta-amino acids and esters; ethyl (S)-(+)-3-aminobutyrate; poly -(R)-(-)-3-hydroxybutyrate (PHB);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient method for the preparation of optically active ethyl P-aminobutyrate from the biopolymer, poly-(R)-(-)3-hydroxybutyrate (PHB) obtained from bacterial cells has been established using chemical transformations: simple recovery of PHB from bacterial cells followed by acidic alcoholysis, tosylation, nucleophilic substitution by azide, and an indium mediated reduction.

引用

页码：498 / 499

页数：2

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