Preparation of optically active β-amino acids from microbial polyester polyhydroxyalkanoates

被引：0
|
作者：
Park, SH
Lee, SH
Lee, SY
机构：
[1] Korea Adv Inst Sci & Technol, Metab & Biomol Engn Natl Res Lab, Dept Chem Engn, Yusong Gu, Taejon 305701, South Korea
[2] ChiroBio Inc, Yusong Gu, Taejon 305301, South Korea
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 2001年 / 11期
关键词：
optically active beta-amino acids and esters; ethyl (S)-(+)-3-aminobutyrate; poly -(R)-(-)-3-hydroxybutyrate (PHB);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method for the preparation of optically active ethyl P-aminobutyrate from the biopolymer, poly-(R)-(-)3-hydroxybutyrate (PHB) obtained from bacterial cells has been established using chemical transformations: simple recovery of PHB from bacterial cells followed by acidic alcoholysis, tosylation, nucleophilic substitution by azide, and an indium mediated reduction.
引用
收藏
页码：498 / 499
页数：2
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