[ReOCl3(PPh3)2] as a substrate for the synthesis of the rhenium(I) carbonyl complexes [Re(CO)2(OAc)(PPh3)2] and [ReCl(CO)3(PPh3)2]

被引：2

作者：

Krawczyk, Monika K. ^{[1
]}

Krawczyk, Marta S. ^{[1
]}

Siczek, Milosz ^{[1
]}

Lis, Tadeusz ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 733卷

关键词：

Rhenium carbonyl complex; Acetic anhydride; Decarbonylation; PENTACARBONYL; PERCHLORATE; LIGANDS;

D O I：

10.1016/j.jorganchem.2013.03.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New preparative methods have been developed for the synthesis of the rhenium(I) carbonyl complexes [Re(CO)(2)(OAc)(PPh3)(2)] (1) and [ReCl(CO)(3)(PPh3)(2)] (2). Acetic anhydride was decarbonylated during the course of its reaction with [ReOCl3(PPh3)(2)], resulting in the formation of the rhenium(I) carbonyl complex [Re(CO)(2)(OAc)(PPh3)(2)] (1), which was subsequently converted almost quantitatively to [ReCl(CO)(3)(PPh3)(2)] (2) via the decarbonylation of its acetate group under acidic conditions. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：60 / 62

页数：3

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[21] REACTION DYNAMICS OF THE TRICOORDINATE INTERMEDIATES RHCL(PPH3)2, IRCL(PPH3)2 AS PROBED BY THE FLASH-PHOTOLYSIS OF THE CARBONYLS MCL(CO)(PPH3)2
WINK, DA
FORD, PC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) : 436 - 442
[22] CARBONYLATION OF METAL OXYGEN BONDS - FORMATION OF CARBALKOXYDICARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM, MEOC(O)IR(CO)2(PPH3)2, (N-PROC(O)IR(CO)2(PPH3)2, (PHOC(O)IR(CO)2(PPH3)2, BY CARBONYLATION OF TRANS-ALKOXYCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM, TRANS-MEOIR(CO)(PPH3)2, N-PROIR(CO)(PPH3)2, PHOIR(CO)(PPH3)2
REES, WM
ATWOOD, JD
[J]. ORGANOMETALLICS, 1985, 4 (02) : 402 - 404
[23] Ligand exchange reactions of ReCl4(PPh3)2, ReOCl3(PPh3)2 and NiCl2(PPh3)2 with acetylacetone thiobenzoylhydrazone.: An unexpected template reaction at the ReO3+ core.: Molecular structures of the resulting oxorhenium(V) and nickel complexes
Sawusch, S
Schilde, U
Lehmann, A
Uhlemann, E
[J]. INORGANICA CHIMICA ACTA, 1998, 277 (02) : 219 - 224
[24] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE IN THE PRESENCE OF RHCL(CO)(PPH3)2 AND IRCL(CO)(PPH3)2
SZYMASZEK, A
PRUCHNIK, FP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 376 (01) : 133 - 140
[25] Silylation of styrene with vinylsilanes catalyzed by RuCl(SiR3)(CO)(PPh3)(2) and RuHCl(CO)(PPh3)(3)
Marciniec, B
Pietraszuk, C
[J]. ORGANOMETALLICS, 1997, 16 (20) : 4320 - 4326
[26] OXIDATION OF THE MOLYBDENUM HYDRIDE CPMO(CO)2(PPH3)H - SYNTHESIS OF CIS-CPMO(CO)2(PPH3)(NCME)+ AND TRANS-CPMO(CO)2(PPH3)(NCME)+ AND THE KINETICS OF THEIR INTERCONVERSION
SMITH, KT
TILSET, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 431 (01) : 55 - 64
[27] DIFLUOROCARBENE COMPLEXES OF RUTHENIUM DERIVED FROM TRIFLUOROMETHYL COMPOUNDS - RUCL2 (CF2) (CO) (PPH3)2, RUCL2 (CFNME2) (CO) (PPH3)2, RUCL2 (CFOME) (CO) (PPH3)2 AND THE STRUCTURE OF RU (CF3) (HGCF3) (CO)2 (PPH3)2
CLARK, GR
HOSKINS, SV
ROPER, WR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 234 (01) : C9 - C12
[28] Action of triphenylphosphine on [Rh(HCOO)(PPh3)2(CO).: A novel synthetic route to [HRh(PPh3)3(CO)]
Varshavsky, YS
Cherkasova, TG
Podkorytov, IS
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (04) : 489 - 491
[29] ON THE REACTION OF REO2I(PPH3)2 WITH PHNCO - SYNTHESIS AND CRYSTAL-STRUCTURES OF REO2I(PPH3)2.CHCL3, [ORE(OCONPH)I(PPH3)]3, RE(NPH)(NH2PH)I2(PPH3)(OCONHPH), AND RE(NPH)(NH2PH)I2(PPH3)(OREO3)
SCHMID, S
STRAHLE, J
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (02): : 235 - 244
[30] SYNTHESIS AND REACTIVITY OF IR2(CO)6(PPH3)2 AND HLR(CO)3PPH3
MALATESTA, L
ANGOLETT.M
CONTI, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 33 (02) : C43 - +

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