Action of triphenylphosphine on [Rh(HCOO)(PPh3)2(CO).: A novel synthetic route to [HRh(PPh3)3(CO)]

被引：6

作者：

Varshavsky, YS

Cherkasova, TG

Podkorytov, IS

机构：

[1] St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia

[2] SV Lebedev Synthet Rubber Res Inst, St Petersburg 198035, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期

关键词：

rhodium; format; carbonyl hydride;

D O I：

10.1016/j.inoche.2004.01.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rhodium(I) carbonyl formato complex, trans-[Rh(HCOO)(PPh3)(2)(CO)], on heating in propanol-2 in the presence of excess triphenylphosphine converts into carbonyl hydride complex, [HRh(PPh3)(3)(CO)], with a good yield. The reaction provides a new and attractive method of synthesis of [HRh(PPh3)(3)(CO)]. (C) 2004 Elsevier B.V. All right reserved.

引用

页码：489 / 491

页数：3

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