Action of triphenylphosphine on [Rh(HCOO)(PPh3)2(CO).: A novel synthetic route to [HRh(PPh3)3(CO)]

被引：6
|
作者：
Varshavsky, YS
Cherkasova, TG
Podkorytov, IS
机构：
[1] St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia
[2] SV Lebedev Synthet Rubber Res Inst, St Petersburg 198035, Russia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期
关键词：
rhodium; format; carbonyl hydride;
D O I：
10.1016/j.inoche.2004.01.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhodium(I) carbonyl formato complex, trans-[Rh(HCOO)(PPh3)(2)(CO)], on heating in propanol-2 in the presence of excess triphenylphosphine converts into carbonyl hydride complex, [HRh(PPh3)(3)(CO)], with a good yield. The reaction provides a new and attractive method of synthesis of [HRh(PPh3)(3)(CO)]. (C) 2004 Elsevier B.V. All right reserved.
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页码：489 / 491
页数：3
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