Composite MOF Foams: The Example of UiO-66/Polyurethane

被引：93
|
作者：
Pinto, Moises L. [1 ,2 ,3 ]
Dias, Sandra [1 ,2 ]
Pires, Joao [1 ,2 ]
机构：
[1] Univ Lisbon, Fac Sci, Dept Chem & Biochem, P-1749016 Lisbon, Portugal
[2] Univ Lisbon, Fac Sci, CQB, P-1749016 Lisbon, Portugal
[3] Univ Aveiro, Dept Chem, CICECO, P-3810193 Aveiro, Portugal
来源：
ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 07期
关键词：
MOP; metal-organic frameworks; polyurethane foam; composite adsorbents; adsorption; UiO-66; METAL-ORGANIC FRAMEWORKS; ADSORBENT MATERIALS; POLYURETHANE FOAMS; ADSORPTION; HKUST-1;
D O I：
10.1021/am303089g
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Composite MOF foams were prepared using a direct synthesis of UiO-66 over a polyurethane foam template. Under optimized conditions, the composite materials maintained the macrostructure and flexibility of the polyurethane foam, and exhibited the microporosity, high surface area, and adsorption properties of the UiO-66. The composite MOF foam has hierarchical porosity and high adsorption capacity for benzene and n-hexane, maintaining more than 70% of the adsorption capacity of the UiO-66.
引用
收藏
页码：2360 / 2363
页数：4
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