UiO-66 MOF and Poly(vinyl cinnamate) Nanofiber Composite Membranes Synthesized by a Facile Three-Stage Process

被引:51
|
作者
Armstrong, Mitchell R. [1 ]
Arredondo, Korinthia Y. Yuriar [1 ]
Liu, Chao-Yuan [1 ]
Stevens, Joshua E. [1 ]
Mayhob, Alexandre [1 ]
Shan, Bohan [1 ]
Senthilnathan, Sethuraman [1 ]
Balzer, Christopher J. [1 ]
Mu, Bin [1 ]
机构
[1] Arizona State Univ, Sch Engn Mat Transport & Energy, Tempe, AZ 85287 USA
关键词
ELECTROSPUN; MATS; STABILITY; SKELETONS; TIME;
D O I
10.1021/acs.iecr.5b03334
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Electrospun poly(vinyl cinnamate),,(PVCi) nanofibers were cross-linked-for varying times to study the impact it has on fiber stability at elevated temperatures and in dimethylformamide solutions. UiO-66 impregnated PVCi was cross linked, and secondary growth of UiO-66 Crystals was performed. The impact of temperature and number of growths was analyzed through powder X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy, A membrane that underwent three growth cycles at 100 degrees C was further characterized for potential uses as a gas membrane through inert gas permeation studies and nitrogen porosimetry.
引用
收藏
页码:12386 / 12392
页数:7
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