Cd(II) and Pb(II) sorption by extracellular polymeric substances (EPS) extracted from anaerobic granular biofilms: Evidence of a pH sorption-edge

被引:55
|
作者
Guibaud, Gilles [1 ]
Bhatia, Divya [1 ,2 ,3 ]
d'Abzac, Paul [1 ]
Bourven, Isabelle [1 ]
Bordas, Francois [1 ]
van Hullebusch, Eric D. [2 ]
Lens, Piet N. L. [3 ]
机构
[1] Univ Limoges, Groupement Rech Eau Sol Environm, F-87060 Limoges, France
[2] Univ Paris Est, Lab Geomat & Environm, F-77454 Marne La Vallee 2, France
[3] UNESCO IHE, Pollut Prevent & Control Core, NL-2601 DA Delft, Netherlands
关键词
Extracellular polymeric substances (EPS); Anaerobic granular sludges; pH sorption edge; Kurbatov model; Cd; Pb; CADMIUM BIOSORPTION; ACTIVATED SLUDGES; CD ADSORPTION; BINDING; EQUILIBRIUM; LEAD; PB; REACTIVITY; COPPER; FE;
D O I
10.1016/j.jtice.2011.12.007
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This work investigates the ability of EPS extracted by cationic exchange resin (CER) from 3 different anaerobic granular sludges to bind Pb or Cd as a function of pH. EPS display a better binding ability for Pb than Cd as it has been often shown in literature. The experimental sorption data show the presence of a pH sorption edge. The experimental data are well fitted by the Kurbatov model. Nevertheless, the molar ratio of proton exchanged with metal ions underlines that other mechanisms are also involved in metal ion sorption by EPS from anaerobic granular sludges. Moreover, the mineral fraction present in extracted EPS and trapped by the organic fraction or under particle form seems to be involved in the metal ions sorption process. (C) 2011 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:444 / 449
页数:6
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