Novel concentration-driven structural interconversion in shape-specific solids supported by the octahedral [Re6(μ3-Se)8]2+ cluster core

被引：50

作者：

Selby, HD ^{[1
]}

Orto, P ^{[1
]}

Carducci, MD ^{[1
]}

Zheng, ZP ^{[1
]}

机构：

[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 24期

关键词：

D O I：

10.1021/ic025925p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A complex containing the face-capped octahedral [Re-6(mu(3)-Se)(8)](2+) cluster core, cis-[Re-6(mu(3)-Se)(8)(PPh3)(4)(4,4'-dipyridyl)(2)](SbF6)(2) (1), is used as a ditopic ligand with an enforced right angle between the two 4,4'-dipyridyl moieties for the coordination of Cd2+ ion. Two coordination polymers, [{Re-6(mu(3)-Se)(8)(PPh3)(4)(4,4'-dipyridyl)(2)}(2){Cd(NO3)(2)}](SbF6)(4).21C(4)H(10)O.21CH(2)Cl(2) (2) and [{Re-6(mu(3)-Se)(8)(PPh3)(4)(4,4'-dipyridyl)(2)}{Cd(NO3)(3)}](NO3).2C(4)H(10)O.CH2Cl2 (3), are obtained. The relative concentration of Cd2+ determines which species is isolated, and the conversion of the first structure into the second is demonstrated experimentally.

引用

页码：6175 / 6177

页数：3

共 45 条

[41] Novel inorganic ionic compounds based on Re6 chalcocyanide cluster complexes:: synthesis and crystal structures of [CuNH3(trien)]2[Re6S8(CN)6]•7H2O, [CuNH3(trien)]2[Re6Se8(CN)6] and [CuNH3(trien)]2[Re6Te8(CN)6]•H2O
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[42] Unexpected ligand substitutions in the cluster core {Re6Se8}:: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4O4Cl6]3•4H2O
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[43] Novel Low Dimensional Cluster Compounds: Syntheses and Crystal Structures of Cs[{Me3Sn}3{Re6Se8(CN)6}], [{Me3Sn(H2O)}2{Me3Sn}{Re6Se8(CN)6}] · H2O, and [(Me3Sn)3(OH)2][{Me3Sn}3{Re6Se8(CN)6}]. pH Control of the Structural Dimensionality
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[J]. Journal of Cluster Science, 2005, 16 : 353 - 365
[44] Novel low dimensional cluster compounds:: syntheses and crystal structures of Cs[{Me3Sn}3{Re6Se8(CN)6}], [{Me3Sn(H2O)}2{Me3Sn}{Re6Se8(CN)6}] • H2O, and [(Me3Sn)3(OH)2][{Me3Sn}3{Re6Se8(CN)6}].: pH control of the structural dimensionality
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[J]. JOURNAL OF CLUSTER SCIENCE, 2005, 16 (03) : 353 - 365
[45] Inertness of the [Re6Se5Cl3]5+ cluster core to substitution by OH- in organic solutions:: synthesis, structural and liquid secondary ion mass spectroscopy characterization of K(H2O)2[Re6Se5Cl9] and (n-Bu4N)[Re6Se5Cl9] and the crystal structure of (n-Bu4N)2[Re6Se6Cl8]
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[J]. NEW JOURNAL OF CHEMISTRY, 2001, 25 (05) : 737 - 740

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