Novel concentration-driven structural interconversion in shape-specific solids supported by the octahedral [Re6(μ3-Se)8]2+ cluster core

被引：50
|
作者：
Selby, HD [1 ]
Orto, P [1 ]
Carducci, MD [1 ]
Zheng, ZP [1 ]
机构：
[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
来源：
INORGANIC CHEMISTRY | 2002年 / 41卷 / 24期
关键词：
D O I：
10.1021/ic025925p
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A complex containing the face-capped octahedral [Re-6(mu(3)-Se)(8)](2+) cluster core, cis-[Re-6(mu(3)-Se)(8)(PPh3)(4)(4,4'-dipyridyl)(2)](SbF6)(2) (1), is used as a ditopic ligand with an enforced right angle between the two 4,4'-dipyridyl moieties for the coordination of Cd2+ ion. Two coordination polymers, [{Re-6(mu(3)-Se)(8)(PPh3)(4)(4,4'-dipyridyl)(2)}(2){Cd(NO3)(2)}](SbF6)(4).21C(4)H(10)O.21CH(2)Cl(2) (2) and [{Re-6(mu(3)-Se)(8)(PPh3)(4)(4,4'-dipyridyl)(2)}{Cd(NO3)(3)}](NO3).2C(4)H(10)O.CH2Cl2 (3), are obtained. The relative concentration of Cd2+ determines which species is isolated, and the conversion of the first structure into the second is demonstrated experimentally.
引用
收藏
页码：6175 / 6177
页数：3
相关论文
共 45 条
  • [21] Bridged multiclusters derived from the face-capped octahedral [Re6III(μ3-Se)8]2+ cluster core
    Selby, HD
    Zheng, ZP
    Gray, TG
    Holm, RH
    [J]. INORGANICA CHIMICA ACTA, 2001, 312 (1-2) : 205 - 209
  • [22] Supramolecular arrays of the [Re6([μ3-Se)8]2+ core-containing clusters mediated by transition metal ions
    Selby, HD
    Orto, P
    Zheng, ZP
    [J]. POLYHEDRON, 2003, 22 (22) : 2999 - 3008
  • [23] Dendritic arrays of [Re6(μ3-Se)8]2+ core-containing clusters:: Exploratory synthesis and electrochemical studies
    Roland, Bryan K.
    Flora, Ware H.
    Selby, Hugh D.
    Armstrong, Neal R.
    Zheng, Zhiping
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (20) : 6620 - 6625
  • [24] Dendritic arrays of [Re6(μ3-Se)8] 2+ core-containing clusters: Exploratory synthesis and electrochemical studies
    Roland, Bryan K.
    Flora, Ware H.
    Selby, Hugh D.
    Armstrong, Neal R.
    Zheng, Zhiping
    [J]. Journal of the American Chemical Society, 2006, 128 (20): : 6620 - 6625
  • [25] Routes to metallodendrimers of the [Re6(μ3-Se)8]2+ core-containing clusters (vol 124, pg 6234, 2002)
    Roland, BK
    Carter, C
    Zheng, ZP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) : 9955 - 9955
  • [26] Dendrimers supported by the [Re6Se8]2+ metal cluster core
    [J]. J Am Chem Soc, 14 (3549):
  • [27] Dendrimers supported by the [Re6Se8]2+ metal cluster core
    Wang, RY
    Zheng, ZP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) : 3549 - 3550
  • [28] Cluster-Bound Nitriles Do Not Click with Organic Azides: Unexpected Formation of Imino Complexes of the [Re6(μ3-Se)8]2+ Core-Containing Clusters
    Tu, Xiaoyan
    Boroson, Ethan
    Truong, Huong
    Munoz-Castro, Alvaro
    Arratia-Perez, Ramiro
    Nichol, Gary S.
    Zheng, Zhiping
    [J]. INORGANIC CHEMISTRY, 2010, 49 (02) : 380 - 382
  • [29] Dendrimers supported by [Re6Se8]2+ metal cluster core.
    Zheng, ZP
    Wang, RY
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U1113 - U1113
  • [30] Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand
    Tu, Xiaoyan
    Truong, Huong
    Nichol, Gary S.
    Zheng, Zhiping
    [J]. INORGANICA CHIMICA ACTA, 2010, 363 (15) : 4189 - 4196
12345