A high yielding, one-pot, triton-B catalyzed synthesis of dithiocarbamates using alcoholic tosylates

被引：29

作者：

Chaturvedi, Devdutt ^{[1
]}

Ray, Suprabhat ^{[1
]}

机构：

[1] Cent Drug Res Inst, Mat & Proc Chem Div, Lucknow 226001, Uttar Pradesh, India

来源：

MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 04期

关键词：

triton-B; carbon disulfide; alcoholic tosylates; dithiocarbamates; thiocarbamation;

D O I：

10.1007/s00706-005-0460-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel process for the one-step chemoselective conversion of alcoholic tosylates into. dithiocarbamates as protected amines was developed using benzyltlimethylammoniumhydroxide (Triton-B) in presence of carbon disulfide. Thus, dithiocarbamates of different amines were prepared in very good to excellent yields. This protocol is mild, chemoselective, and efficient compared to other reported methods.

引用

页码：465 / 469

页数：5

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