A selectivity-driven supramolecular polymerization of an AB monomer

被引：113
|
作者：
Scherman, OA [1 ]
Ligthart, GBWL [1 ]
Sijbesma, RP [1 ]
Meijer, EW [1 ]
机构：
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
directionality; hydrogen bonds; metathesis; ring-opening polymerization; supramolecular polymers;
D O I：
10.1002/anie.200504192
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA + BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2072 / 2076
页数：5
相关论文
共 50 条
  • [41] Studies on the atom transfer radical polymerization of a maleimide AB* monomer and modification of the halogen end groups
    Ren, Q
    Jiang, BB
    Zhang, DL
    Yu, Q
    Fang, JB
    Yang, Y
    Chen, JH
    EUROPEAN POLYMER JOURNAL, 2005, 41 (11) : 2742 - 2752
  • [42] Kinetic modeling of hyperbranched polymerization involving an AB2 monomer reacting with substitution effect
    Galina, H
    Lechowicz, JB
    Walczak, M
    MACROMOLECULES, 2002, 35 (08) : 3253 - 3260
  • [43] Kinetic model of hyperbranched polymers formed by the polymerization of AB2 monomer with a substitution effect
    Cheng, KC
    Don, TM
    Guo, WJ
    Chuang, TH
    POLYMER, 2002, 43 (23) : 6315 - 6322
  • [44] Pathway Complexity in Nanotubular Supramolecular Polymerization: Metal-Organic Nanotubes with a Planar-Chiral Monomer
    Zhao, Yingluo
    Kawano, Hiroko
    Yamagishi, Hiroshi
    Otake, Saya
    Itoh, Yoshimitsu
    Huang, Hubiao
    Meijer, E. W.
    Aida, Takuzo
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (25) : 13920 - 13928
  • [45] Homochiral supramolecular polymerization of an "S''-shaped chiral monomer: Translation of optical purity into molecular weight distribution
    Ishida, Y
    Aida, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) : 14017 - 14019
  • [46] Supramolecular Polymerization at Low Monomer Concentrations: Enhancing Intermolecular Interactions and Suppressing Cyclization by Rational Molecular Design
    Liu, Yiliu
    Fang, Ruochen
    Tan, Xinxin
    Wang, Zhiqiang
    Zhang, Xi
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (49) : 15650 - 15654
  • [47] Supramolecular polymerization and gel formation of Bis(merocyanine) dyes driven by dipolar aggregation
    Yao, S
    Beginn, U
    Gress, T
    Lysetska, M
    Würthner, F
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (26) : 8336 - 8348
  • [48] Self-assembly Strategies Driven by Supramolecular RAFT Polymerization: Pseudorotaxanes and Nanosheets
    Wang, Xiaowei
    Zhang, Jiayi
    Qu, Jiajun
    Li, Jun
    Feng, Anchao
    Liu, Jun
    CHINESE JOURNAL OF CHEMISTRY, 2025,
  • [49] Supramolecular polymerization and gel formation of bis(merocyanine) dyes driven by dipolar aggregation
    Yao, Sheng
    Beginn, Uwe
    Gress, Tobias
    Lysetska, Marina
    Würthner, Frank
    Journal of the American Chemical Society, 2004, 126 (26): : 8336 - 8348
  • [50] SUPRAMOLECULAR CHEMISTRY Living supramolecular polymerization
    Mukhopadhyay, Rahul Dev
    Ajayaghosh, Ayyappanpillai
    SCIENCE, 2015, 349 (6245) : 241 - 242
12345