A selectivity-driven supramolecular polymerization of an AB monomer

被引：113
|
作者：
Scherman, OA [1 ]
Ligthart, GBWL [1 ]
Sijbesma, RP [1 ]
Meijer, EW [1 ]
机构：
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
directionality; hydrogen bonds; metathesis; ring-opening polymerization; supramolecular polymers;
D O I：
10.1002/anie.200504192
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA + BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2072 / 2076
页数：5
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