A selectivity-driven supramolecular polymerization of an AB monomer

被引：113
|
作者：
Scherman, OA [1 ]
Ligthart, GBWL [1 ]
Sijbesma, RP [1 ]
Meijer, EW [1 ]
机构：
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期
关键词：
directionality; hydrogen bonds; metathesis; ring-opening polymerization; supramolecular polymers;
D O I：
10.1002/anie.200504192
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA + BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2072 / 2076
页数：5
相关论文
共 50 条
  • [1] Influence of selectivity on the supramolecular polymerization of AB-type polymers capable of both AA and AB interactions
    Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, Netherlands
    不详
    Journal of the American Chemical Society, 2008, 130 (41): : 13755 - 13764
  • [2] Selectivity-Driven Design of the Ag-Cu Alloys for the Ethylene Epoxidation
    Xu, Haoxiang
    Zhu, Lin
    Nan, Yang
    Xie, Yuan
    Zhu, Jiqin
    Fortunelli, Alessandro
    Cheng, Daojian
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (29) : 12996 - 13006
  • [3] Externally Regulated Specific Molecular Recognition Driven Pathway Selectivity in Supramolecular Polymerization
    Chakraborty, Anwesha
    Manna, Rabindra Nath
    Paul, Ankan
    Ghosh, Suhrit
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (44) : 11458 - 11467
  • [4] Influence of selectivity on the supramolecular polymerization of AB-type polymers capable of both A•A and A•B interactions
    de Greef, Tom F. A.
    Ercolani, Gianfranco
    Ligthart, G. B. W. L.
    Meijer, E. W.
    Sijbesma, Rint P.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (41) : 13755 - 13764
  • [5] Living supramolecular polymerization based on reversible deactivation of a monomer by using a 'dummy' monomer
    Fukui, Tomoya
    Sasaki, Norihiko
    Takeuchi, Masayuki
    Sugiyasu, Kazunori
    CHEMICAL SCIENCE, 2019, 10 (28) : 6770 - 6776
  • [6] Progress towards synthesis of an AB monomer for a Wittig polymerization
    Smith, Harrison
    Posey, Rebekah
    Huddleston, Noah
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [7] THE SYNTHESIS AND POLYMERIZATION OF A RIGID-ROD AB MONOMER
    CHEN, JP
    FELD, WA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 235 - POLY
  • [8] Kinetic models of the polymerization of an AB2 monomer
    Galina, H
    Lechowicz, JB
    Kaczmarski, K
    MACROMOLECULAR THEORY AND SIMULATIONS, 2001, 10 (03) : 174 - 178
  • [9] A case study of monomer design for controlled/living supramolecular polymerization
    Sugiyasu, Kazunori
    POLYMER JOURNAL, 2021, 53 (08) : 865 - 875
  • [10] Elucidating the Impact of Monomer Structure on the Supramolecular Polymerization of Diketopyrrolopyrrole Derivatives
    Yang, Xiwen
    Lu, Peijun
    Liu, Yiliu
    MACROMOLECULAR RAPID COMMUNICATIONS, 2025,
12345