Reversible cleavage and recombination of an acetylenic carbon-carbon bond on a tetrairon cluster coupled with a two-electron redox reaction

被引：25
|
作者：
Okazaki, M [1 ]
Ohtani, T
Ogino, H
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
[2] Univ Air, Miyagi Study Ctr, Sendai, Miyagi 9808577, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期
关键词：
D O I：
10.1021/ja049720m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two-electron reduction of [(η5-C5H4Me)4Fe4(μ3-CH)2(μ3-CO)2](PF6)2 (1) results in the coupling of two methylidyne ligands to form (η5-C5H4Me)4Fe4(HCCH)(μ3-CO)2 (2), the two-electron oxidation of which reproduces 1. Structures of 1 and 2 were determined by X-ray diffraction analysis. Copyright © 2004 American Chemical Society.
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页码：4104 / 4105
页数：2
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