Reversible cleavage and recombination of an acetylenic carbon-carbon bond on a tetrairon cluster coupled with a two-electron redox reaction

被引：25
|
作者：
Okazaki, M [1 ]
Ohtani, T
Ogino, H
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
[2] Univ Air, Miyagi Study Ctr, Sendai, Miyagi 9808577, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期
关键词：
D O I：
10.1021/ja049720m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two-electron reduction of [(η5-C5H4Me)4Fe4(μ3-CH)2(μ3-CO)2](PF6)2 (1) results in the coupling of two methylidyne ligands to form (η5-C5H4Me)4Fe4(HCCH)(μ3-CO)2 (2), the two-electron oxidation of which reproduces 1. Structures of 1 and 2 were determined by X-ray diffraction analysis. Copyright © 2004 American Chemical Society.
引用
收藏
页码：4104 / 4105
页数：2
相关论文
共 50 条
  • [31] Performance of Block Correlated Coupled Cluster Method with the CASSCF Reference Function for Carbon-Carbon Bond Breaking in Hydrocarbons
    Shen, Jun
    Fang, Tao
    Li, Shuhua
    ADVANCES IN THE THEORY OF ATOMIC AND MOLECULAR SYSTEMS: CONCEPTUAL AND COMPUTATIONAL ADVANCES IN QUANTUM CHEMISTRY, 2009, 19 : 241 - 255
  • [32] Lanthanide-Catalyzed Reversible Alkynyl Exchange by Carbon-Carbon Single-Bond Cleavage Assisted by a Secondary Amino Group
    Shao, Yinlin
    Zhang, Fangjun
    Zhang, Jie
    Zhou, Xigeng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (38) : 11485 - 11489
  • [33] An Enzymatic Carbon-Carbon Bond Cleavage and Aldol Reaction Cascade Converts an Angular Scaffold into the Linear Tetracyclic Core of Ochraceopones
    Li, Yanqin
    Cong, Mengjing
    Wang, Wengui
    Zhang, Xiufeng
    Zhu, Yiguang
    Song, Yongxiang
    Zhang, Wenjun
    Xiao, Hua
    Liu, Yonghong
    Zhang, Changsheng
    Wang, Junfeng
    Yan, Yan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (22)
  • [34] The mechanism of the carbon-carbon bond cleavage step of the cytochrome P450 19A1 aromatase reaction
    Yoshimoto, Francis
    Guengerich, F. Peter
    DRUG METABOLISM REVIEWS, 2015, 47 : 37 - 38
  • [35] Mechanistic Studies of the O2-Dependent Aliphatic Carbon-Carbon Bond Cleavage Reaction of a Nickel Enolate Complex
    Berreau, Lisa M.
    Borowski, Tomasz
    Grubel, Katarzyna
    Allpress, Caleb J.
    Wikstrom, Jeffrey P.
    Germain, Meaghan E.
    Rybak-Akimova, Elena V.
    Tierney, David L.
    INORGANIC CHEMISTRY, 2011, 50 (03) : 1047 - 1057
  • [36] Regioselective carbon-carbon bond cleavage of an open-cage diketone derivative of [60]fullerene by reaction with aromatic hydrazones
    Iwamatsu, S
    Kuwayama, T
    Kobayashi, K
    Nagase, S
    Murata, S
    SYNTHESIS-STUTTGART, 2004, (18): : 2962 - 2964
  • [37] NOVEL CARBON-CARBON BOND-CLEAVAGE REACTION OF PENEM ANTIBIOTIC BY CLASS-C BETA-LACTAMASES
    TANAKA, R
    NAMIKAWA, K
    NAKATSUKA, T
    ADACHI, H
    YOSHIDA, T
    SUGITA, O
    ISHIGURO, M
    JOURNAL OF ANTIBIOTICS, 1994, 47 (08): : 945 - 948
  • [38] Ru(II)-Catalyzed C-H Activation and Annulation Reaction via Carbon-Carbon Triple Bond Cleavage
    Prakash, Rashmi
    Bora, Bidisha R.
    Boruah, Romesh C.
    Gogoi, Sanjib
    ORGANIC LETTERS, 2018, 20 (08) : 2297 - 2300
  • [39] CARBON-CARBON BOND-CLEAVAGE REACTIONS OF 1,2-DIAMINES INITIATED BY PHOTOINDUCED ELECTRON-TRANSFER
    KELLETT, MA
    WHITTEN, DG
    RESEARCH ON CHEMICAL INTERMEDIATES, 1995, 21 (06) : 587 - 611
  • [40] Storage and release of two electrons from an electron-rich carbon-carbon bond: boron mediated reversible coupling of DMAP and 9-azajulolidine
    Cui, Yunshu
    Xiang, Libo
    Wang, Junyi
    Li, Chunlei
    Hao, Wei
    Ye, Qing
    CHEMICAL COMMUNICATIONS, 2020, 56 (50) : 6794 - 6797
12345