Functionalized Coordination Space in Metal-Organic Frameworks

被引：96
|
作者：
Fischer, Roland A. [1 ]
Woell, Christof [1 ]
机构：
[1] Ruhr Univ Bochum, D-44780 Bochum, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 43期
关键词：
fluorinated ligands; host-guest systems; organic-inorganic hybrid composites; porous materials;
D O I：
10.1002/anie.200801612
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Two significant advances in the development of metal-organic frameworks (MOFs) are perfluoro MOFs (see structure) with an outstanding volumetric gas uptake and hysteretic sorption of dihydrogen. The modular synthesis of functional MOFs involves a two-component framework, in which one component is an integral component of the framework and the other can be exchanged after formation of the matrix. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8164 / 8168
页数：5
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