Fluorine-functionalized metal-organic frameworks and porous coordination polymers

被引:95
|
作者
Noro, Shin-ichiro [1 ,2 ]
Nakamura, Takayoshi [1 ]
机构
[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido, Japan
[2] Hokkaido Univ, Creat Res Inst, Sapporo, Hokkaido, Japan
基金
日本科学技术振兴机构;
关键词
GATE ADSORPTION; SOLID-SOLUTIONS; GAS-ADSORPTION; CO2; ADSORPTION; SORPTION; PLATFORM; PORES; MOF; REMOVAL; DESIGN;
D O I
10.1038/am.2017.165
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fluorine, the element with the highest electronegativity and low electric polarizability, can produce a variety of characteristics, including specific adsorption sites for molecules as well as flexibility to the host materials. In this review, we will introduce fluorine-functionalized metal-organic frameworks/porous coordination polymers that show unique and unprecedented structures, structural transformations, and gas and vapor adsorption/separation properties derived from the fluorine characteristics.
引用
收藏
页码:e433 / e433
页数:14
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