Modified starch with bis(2-hydroxyethyl) terephthalate: synthesis, characterization and elaboration of films

被引：7
|
作者：
Ramirez-Centeno, Silvia [1 ]
Marcos-Fernandez, Angel [2 ]
Aparicio-Saguilan, Alejandro [1 ]
Navarro-Crespo, Rodrigo [2 ]
Eduardo Baez-Garcia, Jose [3 ]
Paramo-Calderon, Delia Esther [1 ]
Ramirez-Hernandez, Aurelio [1 ]
机构：
[1] Univ Papaloapan, Dept Quim, Circuito Cent 200, Tuxtepec 68301, Oaxaca, Mexico
[2] Inst Ciencia & Tecnol Polimeros ICTP, C Juan de la Cierva 3, Madrid 28006, Spain
[3] Univ Guanajuato, Div Ciencias Exactas, Dept Quim, Noria Alta S-N, Guanajuato 36050, Mexico
来源：
JOURNAL OF POLYMER RESEARCH | 2020年 / 27卷 / 09期
关键词：
BHET; Banana starch; Modified starch; Films; BANANA STARCH; 2; VARIETIES; POLY(ETHYLENE-TEREPHTHALATE); DEGRADATION; BIODEGRADATION; OPTIMIZATION; COPOLYMER; CHITOSAN; BEHAVIOR; BLENDS;
D O I：
10.1007/s10965-020-02249-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Banana starch was modified with B bis(2-hydroxyethyl) terephthalate and its instrumental characterization allowed to propose a chemical structure. In the carbon 6 (C6) of the starch the modification reaction was carried out. The morphology of starch changes due to its chemical modification. The modified starch showed a lower crystallinity and thermal stability, compared to the native starch favoring its film formation. The electrical conductivity of the modified starch films was 2.7 times higher than that for the native starch film. The aqueous hydrolysis of the modified starch films was carried out obtaining a degradation of 77% in a determined time. Modified starch films present different mechanical properties compared to native starch film. These results have high application potential to be used in PET degradation products.
引用
收藏
页数：12
相关论文
共 50 条
  • [41] Novel synthesis, characterization and application of dibutyrate bis(2-hydroxyethyl) terephthalamide as a plasticizer in PVC compounding
    Parab, Yogesh S.
    Wasekar, Parag A.
    Mhaske, Shashank T.
    Shukla, Sanjeev R.
    POLYMER BULLETIN, 2014, 71 (10) : 2695 - 2707
  • [42] Synthesis and characterization of a nickel(II) complex with bis(benzimidazol-2-ylmethyl)(2-hydroxyethyl)amine
    Yin, LH
    Bu, PY
    Cheng, P
    Li, J
    Yan, SP
    Jiang, ZH
    Liao, DZ
    JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (05) : 537 - 543
  • [43] Novel synthesis, characterization and application of dibutyrate bis(2-hydroxyethyl) terephthalamide as a plasticizer in PVC compounding
    Yogesh S. Parab
    Parag A. Wasekar
    Shashank T. Mhaske
    Sanjeev R. Shukla
    Polymer Bulletin, 2014, 71 : 2695 - 2707
  • [44] Bis(2-hydroxyethyl)ammonium picrate
    Nagapandiselvi, Perumal
    Gopalakrishnan, Rengasamy
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1455 - +
  • [45] SUBSTITUTION PATTERNS OF 0-(2-HYDROXYETHYL)STARCH AND 0-(2-HYDROXYETHYL)DEXTRAN
    DEBELDER, AN
    NORRMAN, B
    CARBOHYDRATE RESEARCH, 1969, 10 (03) : 391 - &
  • [46] N,N-Bis(2-hydroxyethyl)formamide as a New Plasticizer for Thermoplastic Starch
    Dai, Hongguang
    Chang, Peter R.
    Yu, Jiugao
    Ma, Xiaofei
    STARCH-STARKE, 2008, 60 (12): : 676 - 684
  • [47] STUDIES ON FORMATION OF POLY(ETHYLENE TEREPHTHALATE) .1. PROPAGATION AND DEGRADATION REACTIONS IN POLYCONDENSATION OF BIS(2-HYDROXYETHYL)TEREPHTHALATE
    TOMITA, K
    POLYMER, 1973, 14 (02) : 50 - 54
  • [48] Bis(2-hydroxyethyl) 2-phenylsuccinate
    Olivieri, Diego
    Tarroni, Riccardo
    Carfagna, Carla
    MOLBANK, 2022, 2022 (04)
  • [49] RAMAN TENSORS FOR THE 1614 AND 633 CM-1 MODES OF BIS(2-HYDROXYETHYL) TEREPHTHALATE
    LEWIS, ELV
    BOWER, DI
    JOURNAL OF RAMAN SPECTROSCOPY, 1987, 18 (01) : 61 - 70
  • [50] Synthesis and properties of pyrazole carbaldehyde bis(2-hydroxyethyl)-dithioacetal hydrochlorides*
    L. K. Papernaya
    A. A. Shatrova
    A. I. Albanov
    E. V. Rudyakova
    G. G. Levkovskaya
    Chemistry of Heterocyclic Compounds, 2012, 47 : 1395 - 1404
12345