Benzylation of benzene with benzyl chloride on iron-containing mesoporous mordenite

被引：22
|
作者：
Leng, Kunyue [1 ]
Sun, Shengnan [1 ]
Wang, Binteng [1 ]
Sun, Lin [1 ]
Xu, Wei [2 ]
Sun, Yinyong [1 ]
机构：
[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China
[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2012年 / 28卷
关键词：
Mesoporous; Mordenite; Iron-containing; Benzyl chloride; Benzylation; FRIEDEL-CRAFTS ALKYLATION; SOLID CATALYSTS; ZEOLITE; FE; SBA-15; DIPHENYLMETHANE; AROMATICS; TOLUENE; GACL3; INCL3;
D O I：
10.1016/j.catcom.2012.08.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Microporous mordenite with a low Si/Al ratio was synthesized by using silicic acid powder as silica source under hydrothermal condition. By treating the mordenite with acid and base, mesoporous mordenite (M-Mor) was obtained, which was characterized by X-ray diffraction (XRD), N-2 sorption experiments, and scanning electron microscopy (SEM). Based on the M-Mor material, iron-containing mesoporous mordenite (Fe-M-Mor) was prepared by ion-exchanged method. The benzylation of benzene by benzyl chloride showed that Fe-M-Mor was a highly active catalyst in this reaction and could be reused. These results indicate that Fe-M-Mor has potential applications in Friedel-Crafts alkylations, especially of large molecules. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：64 / 68
页数：5
相关论文
共 50 条
  • [31] Catalytic activity of iron-containing polymers in hydroxylation of benzene with hydrogen peroxide
    N. I. Rudakova
    M. V. Klyuev
    Yu. G. Erykalov
    D. N. Ramazanov
    Russian Journal of General Chemistry, 2007, 77 : 911 - 914
  • [32] Catalytic activity of iron-containing polymers in hydroxylation of benzene with hydrogen peroxide
    Rudakova, N. I.
    Klyuev, M. V.
    Erykalov, Yu. G.
    Ramazanov, D. N.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (05) : 911 - 914
  • [33] Magnetic properties and catalytic performance of iron-containing mesoporous molecular sieves
    Elias, Veronica R.
    Oliva, Marcos I.
    Urreta, Silvia E.
    Silvetti, Silvia P.
    Sapag, Karim
    Mudarra Navarro, Azucena M.
    Casuscelli, Sandra G.
    Eimer, Griselda A.
    APPLIED CATALYSIS A-GENERAL, 2010, 381 (1-2) : 92 - 100
  • [34] Synthesis and characterisation of iron-containing SBA-15 mesoporous silica
    Martinez, F
    Han, YJ
    Stucky, G
    Sotelo, JL
    Ovejero, G
    Melero, JA
    IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B, 2002, 142 : 1109 - 1116
  • [35] Hydroxylation of Phenol on Iron-Containing Mesoporous Silica with Hierarchical Macroporous Architecture
    Kamegawa, Takashi
    Ando, Takahiro
    Ishiguro, Yasushi
    Yamashita, Hiromi
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2015, 88 (04) : 572 - 574
  • [36] Iron-Containing Titania Photocatalyst Prepared by the Sonophotodeposition Method for the Oxidation of Benzyl Alcohol
    Magdziarz, Agnieszka
    Colmenares, Juan C.
    Chernyayeva, Olga
    Kurzydlowski, Krzysztof
    Grzonka, Justyna
    CHEMCATCHEM, 2016, 8 (03) : 536 - 539
  • [37] IRON-CONTAINING DRUGS
    BROWN, DA
    CHIDAMBARAM, MV
    METAL IONS IN BIOLOGICAL SYSTEMS, 1982, 14 : 125 - 177
  • [38] IRON-CONTAINING ANTIBIOTICS
    NEILANDS, JB
    VALENTA, JR
    METAL IONS IN BIOLOGICAL SYSTEMS, 1985, 19 : 313 - 333
  • [39] Iron-containing ureases
    Proshlyakov, Denis A.
    Farrugia, Mark A.
    Proshlyakov, Yegor D.
    Hausinger, Robert P.
    COORDINATION CHEMISTRY REVIEWS, 2021, 448
  • [40] Replacing benzyl chloride with benzyl alcohol in heterogeneous catalytic benzylation of aromatic compounds
    Candu, Natalia
    Wuttke, Stefan
    Kemnitz, Erhard
    Coman, Simona M.
    Parvulescu, Vasile I.
    PURE AND APPLIED CHEMISTRY, 2012, 84 (03) : 427 - 437
12345