Benzylation of benzene with benzyl chloride on iron-containing mesoporous mordenite

被引：22

作者：

Leng, Kunyue ^{[1
]}

Sun, Shengnan ^{[1
]}

Wang, Binteng ^{[1
]}

Sun, Lin ^{[1
]}

Xu, Wei ^{[2
]}

Sun, Yinyong ^{[1
]}

机构：

[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China

[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2012年 / 28卷

关键词：

Mesoporous; Mordenite; Iron-containing; Benzyl chloride; Benzylation; FRIEDEL-CRAFTS ALKYLATION; SOLID CATALYSTS; ZEOLITE; FE; SBA-15; DIPHENYLMETHANE; AROMATICS; TOLUENE; GACL3; INCL3;

D O I：

10.1016/j.catcom.2012.08.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microporous mordenite with a low Si/Al ratio was synthesized by using silicic acid powder as silica source under hydrothermal condition. By treating the mordenite with acid and base, mesoporous mordenite (M-Mor) was obtained, which was characterized by X-ray diffraction (XRD), N-2 sorption experiments, and scanning electron microscopy (SEM). Based on the M-Mor material, iron-containing mesoporous mordenite (Fe-M-Mor) was prepared by ion-exchanged method. The benzylation of benzene by benzyl chloride showed that Fe-M-Mor was a highly active catalyst in this reaction and could be reused. These results indicate that Fe-M-Mor has potential applications in Friedel-Crafts alkylations, especially of large molecules. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：64 / 68

页数：5

共 50 条

[21] Liquid-phase benzylation of toluene by benzyl alcohol over micro-mesoporous hierarchical mordenite zeolite
Koshti, Hardik
Bandyopadhyay, Rajib
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023,
[22] Self-assembled iron-containing mordenite monolith for carbon dioxide sieving
Zhou, Yu
Zhang, Jianlin
Wang, Lei
Cui, Xili
Liu, Xiaoling
Wong, Sie Shing
An, Hua
Yan, Ning
Xie, Jingyan
Yu, Cong
Zhang, Peixin
Du, Yonghua
Xi, Shibo
Zheng, Lirong
Cao, Xingzhong
Wu, Yajing
Wang, Yingxia
Wang, Chongqing
Wen, Haimeng
Chen, Lei
Xing, Huabin
Wang, Jun
SCIENCE, 2021, 373 (6552) : 315 - +
[23] Mg-Fe-hydrotalcite as catalyst for the benzylation of benzene and other aromatics by benzyl chloride reactions
Tahir, N.
Abdelssadek, Z.
Halliche, D.
Saadi, S.
Chebout, R.
Cherifi, O.
Bachari, K.
SURFACE AND INTERFACE ANALYSIS, 2008, 40 (3-4) : 254 - 258
[24] High catalytic reactivity of Fe-p-o catalysts for benzylation of benzene with benzyl chloride
Zhang, Xin
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
[25] The enhanced activity of Sb after supporting on K10 in the benzylation of benzene using benzyl chloride and benzyl alcohol
Deshpande, AB
Bajpai, AR
Samant, SD
APPLIED CATALYSIS A-GENERAL, 2001, 209 (1-2) : 229 - 235
[26] Reaction kinetics of benzylation of benzene with benzyl chloride on sulfate-treated metal oxide catalysts
Koyande, SN
Jaiswal, RG
Jayaram, RV
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (03) : 908 - 913
[27] Mechanism of selective benzene hydroxylation catalyzed by iron-containing zeolites
Snyder, Benjamin E. R.
Bols, Max L.
Rhoda, Hannah M.
Vanelderen, Pieter
Bottger, Lars H.
Braun, Augustin
Yan, James J.
Hadt, Ryan G.
Babicz, Jeffrey T., Jr.
Hu, Michael Y.
Zhao, Jiyong
Alp, E. Ercan
Hedman, Britt
Hodgson, Keith O.
Schoonheydt, Robert A.
Sels, Bert F.
Solomon, Edward I.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2018, 115 (48) : 12124 - 12129
[28] MoOx and WOx conjugated iron phosphate nanotubes catalysts for benzylation of benzene using benzyl alcohol
Narasimharao, Katabathini
Mokhtar, Mohamed
Al-Mutairi, Ebtesam
CATALYSIS COMMUNICATIONS, 2022, 164
[29] EFFECT OF ULTRASOUND TREATMENT ON MAGNETIC AND CATALYTIC PROPERTIES OF IRON-CONTAINING MORDENITE IN THE REACTION OF BENZENE TO PHENOL OXIDATION BY HYDROGEN PEROXIDE IN LIQUID PHASE
Gasymova, Lala Kh
PROCESSES OF PETROCHEMISTRY AND OIL REFINING, 2019, 20 (04): : 476 - 485
[30] Sol-gel synthesized Fe-P-O catalyst for the benzylation of benzene with benzyl chloride
Lin, Tao
Zhang, Xin
Li, Rong
Zhang, Guiquan
Bai, Ting
MATERIALS AND DESIGN, PTS 1-3, 2011, 284-286 : 2141 - 2145

← 1 2 3 4 5 →