The synthesis and molecular structure of the first two-coordinate, dinuclear σ-bonded mercury(I) RHgHgR compound

被引：0
|
作者：
Bravo-Zhivotovskii, D [1 ]
Yuzefovich, M
Bendikov, M
Klinkhammer, K
Apeloig, Y
机构：
[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[2] Technion Israel Inst Technol, Lise Meitner Minerva Ctr Computat Quantum Chem, IL-32000 Haifa, Israel
[3] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 08期
关键词：
mercury; silicon;
D O I：
10.1002/(SICI)1521-3773(19990419)38:8<1100::AID-ANIE1100>3.0.CO;2-N
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A linear Si-Hg-Hg-Si arrangement and a Hg-Hg distance of 265.69 pm are exhibited by the first two-coordinate, dinuclear σ-bonded organomercury(I) compound 1. It was formed unexpectedly in the reaction of two equivalents of the silane (Me3SiMe2Si)3SiH with tBu2Hg. In contrast if the reagents are allowed to react in a 1:1 ratio the expected mercury(II) compound (Me3SiMe2Si)3SiHgtBu is obtained.
引用
收藏
页码：1100 / 1102
页数：3
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