The synthesis and molecular structure of the first two-coordinate, dinuclear σ-bonded mercury(I) RHgHgR compound

被引：0

作者：

Bravo-Zhivotovskii, D ^{[1
]}

Yuzefovich, M

Bendikov, M

Klinkhammer, K

Apeloig, Y

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Lise Meitner Minerva Ctr Computat Quantum Chem, IL-32000 Haifa, Israel

[3] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 08期

关键词：

mercury; silicon;

D O I：

10.1002/(SICI)1521-3773(19990419)38:8<1100::AID-ANIE1100>3.0.CO;2-N

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A linear Si-Hg-Hg-Si arrangement and a Hg-Hg distance of 265.69 pm are exhibited by the first two-coordinate, dinuclear σ-bonded organomercury(I) compound 1. It was formed unexpectedly in the reaction of two equivalents of the silane (Me3SiMe2Si)3SiH with tBu2Hg. In contrast if the reagents are allowed to react in a 1:1 ratio the expected mercury(II) compound (Me3SiMe2Si)3SiHgtBu is obtained.

引用

页码：1100 / 1102

页数：3

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