Germylenes derived from pyridine-containing diols: reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone

被引：2

作者：

Huang, M. ^{[1
]}

Kireenko, M. M. ^{[1
]}

Zaitsev, K. V. ^{[1
]}

Oprunenko, Yu. F. ^{[1
]}

Churakov, A. V. ^{[2
]}

Karlov, S. S. ^{[1
]}

Zaitseva, G. S. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Moscow 119992, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2012年 / 47卷 / 12期

关键词：

germylenes; hypervalent germanium; pyridine-containing diols; 1,4-cycloaddition; oxidation; X-ray structural analysis; GERMANIUM; GERMOCANES; COMPLEXES; AMIDES; SN;

D O I：

10.1007/s10593-012-0950-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study was carried out on the behavior of monomeric germylenes derived from pyridine-containing diols in reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone. It was found that the germanium atom increases its oxidation state to 4+ in these reactions. The structure of the product of the reaction with 9,10-phenanthrenequinone was confirmed by X-ray structural analysis, which showed a transannular germanium-nitrogen interaction in this product.

引用

页码：1584 / 1589

页数：6

共 44 条

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