Germylenes derived from pyridine-containing diols: reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone

被引：2

作者：

Huang, M. ^{[1
]}

Kireenko, M. M. ^{[1
]}

Zaitsev, K. V. ^{[1
]}

Oprunenko, Yu. F. ^{[1
]}

Churakov, A. V. ^{[2
]}

Karlov, S. S. ^{[1
]}

Zaitseva, G. S. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Moscow 119992, Russia

[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2012年 / 47卷 / 12期

关键词：

germylenes; hypervalent germanium; pyridine-containing diols; 1,4-cycloaddition; oxidation; X-ray structural analysis; GERMANIUM; GERMOCANES; COMPLEXES; AMIDES; SN;

D O I：

10.1007/s10593-012-0950-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study was carried out on the behavior of monomeric germylenes derived from pyridine-containing diols in reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone. It was found that the germanium atom increases its oxidation state to 4+ in these reactions. The structure of the product of the reaction with 9,10-phenanthrenequinone was confirmed by X-ray structural analysis, which showed a transannular germanium-nitrogen interaction in this product.

引用

页码：1584 / 1589

页数：6

共 44 条

[21] PHOTOCHEMICAL REACTIONS OF DIKETONES .2. 1,2-ADDITION OF SUBSTITUTED TOLUENES TO 9,10-PHENANTHRENEQUINONE
RUBIN, MB
ZWITKOWI.P
JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (08): : 2362 - &
[22] CYCLOADDITION REACTIONS OF CYCLOOCTYNE WITH 9,10-PHENANTHRENEQUINONE AND 3,5-DI-TERT-BUTYL-ORTHO-BENZOQUINONE
VERBOOM, W
BOS, HJT
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1981, 100 (05): : 207 - 213
[23] Reactions of 9,10-phenanthrenequinone and its nitro derivatives with acetone in the presence of Al2O3
R. V. Linko
V. K. Belsky
A. V. Varlamov
B. E. Zaitsev
A. I. Chernyshev
Russian Chemical Bulletin, 2001, 50 : 1625 - 1629
[24] SECONDARY MOLD METABOLITES .32. A REINVESTIGATION OF THE STRUCTURE OF BIRULOQUINONE, A 9,10-PHENANTHRENEQUINONE ISOLATED FROM MYCOSPHAERELLA-RUBELLA
ARNONE, A
NASINI, G
DEPAVA, OV
PHYTOCHEMISTRY, 1991, 30 (08) : 2729 - 2731
[25] Dual Tuning of Emission Color and Electron Injection Properties Through in-situ Chemical Reaction in a Conjugated Polymer Containing 9,10-Phenanthrenequinone
Wang, Zhiming
Lu, Ping
Zhang, Wensi
Shen, Fangzhong
Hanif, Muddasir
Ma, Yuguang
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (23) : 2029 - 2036
[26] STUDIES ON THE OXYGENOLYSIS OF 9,10-PHENANTHRENEQUINONE BY CUXL (X = CL OR BR - L = PYRIDINE, 2,2'-BIPYRIDINE, AND 1,10-PHENANTHROLINE) COMPLEXES
SPEIER, G
TYEKLAR, Z
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (09): : 1995 - 2000
[27] Complete H-1- and C-13-NMR spectral data of piloquinone, a 9,10-phenanthrenequinone derivative from Streptomyces pilosus
Jokela, R
Lounasmaa, M
PLANTA MEDICA, 1997, 63 (01) : 85 - 86
[28] KETO OXETANES PRODUCED FROM PHOTOCYCLOADDITION OF ORTHO-QUINONE AND THEIR THERMOLYSIS - REACTION OF 9,10-PHENANTHRENEQUINONE WITH INTERNALLY HIGHLY STRAINED CYCLIC OLEFINS
MARUYAMA, K
MURAOKA, M
NARUTA, Y
JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (05): : 983 - 989
[29] Photochemical hydrogen transfer from bis(i-propylcyclopentadienyl) tungsten dihydride to 9,10-phenanthrenequinone induced by outer sphere charge transfer excitation
Kunkely, H
Kunkely, H
INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (06) : 200 - 202
[30] Two novel oxomolybdenum complexes derived from the reaction of chlorotrisulfidomolybdate precursor with a pyridine-containing tridentate ligand
Wei, Zhenhong
Long, Li
Wei, Junming
Liu, Xiaoming
INORGANICA CHIMICA ACTA, 2011, 375 (01) : 320 - 323

← 1 2 3 4 5 →