Sn-Cu Nanocomposite Anodes for Rechargeable Sodium-Ion Batteries

被引：174

作者：

Lin, Yong-Mao ^{[1
]}

Abel, Paul R. ^{[1
]}

Gupta, Asha ^{[4
,5
]}

Goodenough, John B. ^{[3
,4
,5
,6
]}

Heller, Adam ^{[1
,3
]}

Mullins, C. Buddie ^{[1
,2
,3
,4
,6
]}

机构：

[1] Univ Texas Austin, McKetta Dept Chem Engn, Austin, TX 78712 USA

[2] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[3] Univ Texas Austin, Ctr Electrochem, Austin, TX 78712 USA

[4] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA

[5] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA

[6] Univ Texas Austin, Ctr Nano & Mol Sci, Austin, TX 78712 USA

来源：

ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 17期

关键词：

tin copper alloy; nanoparticles; anode; Na-ion battery; FLUOROETHYLENE CARBONATE; HIGH-CAPACITY; LITHIUM; PERFORMANCE; ELECTROLYTE; CHALLENGES; INSERTION; STORAGE; SIZE;

D O I：

10.1021/am4023994

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Sn0.9Cu0.1 nanoparticles were synthesized via a surfactant-assisted wet chemistry method, which were then investigated as an anode material for ambient temperature rechargeable sodium ion batteries. The Sn0.9Cu0.1 nanoparticle-based electrodes exhibited a stable capacity of greater than 420 mA h g(-1) at 0.2 C rate, retaining 97% of their maximum observed capacity after 100 cycles of sodium insertion/deinsertion. Their performance is considerably superior to electrodes made with either Sn nanoparticles or Sn microparticles.

引用

页码：8273 / 8277

页数：5

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