Nickel-catalyzed hydrodehalogenation of aryl halides

被引：41

作者：

Weidauer, Maik ^{[1
]}

Irran, Elisabeth ^{[2
]}

Someya, Chika I. ^{[1
]}

Haberberger, Michael ^{[1
]}

Enthaler, Stephan ^{[1
]}

机构：

[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany

[2] Tech Univ Berlin, Inst Chem Metalorgan & Inorgan Mat, D-10623 Berlin, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 729卷

关键词：

Catalysis; Nickel complexes; Hydrodehalogenation; Aryl halides; Alkyl halides; NI-AL CLUSTERS; REDUCTIVE DEHALOGENATION; AROMATIC CHLORIDES; GRIGNARD-REAGENTS; BOND ACTIVATION; ORGANIC HALIDES; C-F; COMPLEXES; HYDRODECHLORINATION; DECHLORINATION;

D O I：

10.1016/j.jorganchem.2013.01.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the present study, the nickel-catalyzed dehalogenation of aryl and alkyl halides with iso-propyl zinc bromide or tert-butylmagnesium chloride has been examined in detail. With a straightforward nickel complex as pre-catalyst good to excellent yields and chemoselectivities were feasible for a variety of aryl and alkyl halides. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：53 / 59

页数：7

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