Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates

被引：38
|
作者：
Sardzinski, Logan W. [1 ]
Wertjes, William C. [1 ]
Schnaith, Abigail M. [1 ]
Kalyani, Dipannita [1 ]
机构：
[1] St Olaf Coll, Dept Chem, Northfield, MN 55057 USA
来源：
ORGANIC LETTERS | 2015年 / 17卷 / 05期
基金：
美国国家卫生研究院;
关键词：
CARBOXYLIC-ACIDS; POTASSIUM POLYFLUOROBENZOATES; ALLYL ARYL; ARYLATION; ETHERIFICATION; ALKENYLATION;
D O I：
10.1021/acs.orglett.5b00241
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds are obtained using these newly developed Ni-catalyzed decarboxylative cross-coupling reactions.
引用
收藏
页码：1256 / 1259
页数：4
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