Hydrothermal alteration associated with the Chicxulub impact crater upper peak-ring breccias

The 66 Ma, similar to 180 km Chicxulub impact structure in the northern Yucatan peninsula and southern Gulf of Mexico is the best-preserved large impact crater on Earth with a well-developed peak ring. The most recent drilling campaign took place offshore during the joint International Ocean Discovery Program - International Continental Scientific Drilling Program (IODP-ICDP) Expedition 364 at site M0077A (21.45 degrees N, 89.95 degrees W) and recovered similar to 830 m of continuous core. Initial examination revealed that the peak-ring comprises four main lithological units (from the base upwards): crystalline basement granitoid rocks (Unit 4); a thin layer of impact melt rocks (Units 3A and B); melt-bearing breccias (Units 2A-C); and post-impact sedimentary rocks (Unit 1). Preliminary analysis of the drill core indicated that hydrothermal alteration has affected all lithologies and is especially pervasive in the melt-bearing breccias of Unit 2 (721.6 to 617.33 meters below sea floor, mbsf). Here we present the first detailed investigation of hydrothermal alteration within the melt-bearing breccias. Alteration phases are predominantly Fe-Mg clay minerals, zeolites, alkali feldspars, calcite and minor sulfides, sulfates, opal and Fe-Ti oxides. Alteration is especially intense proximal to lithologic contacts, particularly at the base of subunit 2B where there is an abrupt increase in host rock porosity similar to 30 m above the impact melt rocks. The pervasiveness of clay minerals and zeolites is attributed to the high amounts of devitrified silicate glass throughout Unit 2. The phases preserved here are consistent with the findings of previous hydrothermal studies in other areas of the Chicxulub structure, and suggest an evolving water-rock system that was alkaline-saline, comparable to seawater-volcanic glass alteration. (C) 2020 Elsevier B.V. All rights reserved.