Stereoselective Synthesis of Conjugated Bisallenols as Precursors of Novel Bis(2,5-dihydrofuran) Derivatives

被引：38
|
作者：
Poonoth, Manojkumar [1 ]
Krause, Norbert [1 ]
机构：
[1] Dortmund Univ Technol, D-44227 Dortmund, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 1-2期
关键词：
bisallenes; chirality transfer; cycloisomerization; gold catalysis; silver catalysis; ANNONACEOUS ACETOGENINS; GOLDEN OPPORTUNITIES; FUNCTIONALIZED 2,5-DIHYDROFURANS; GOLD(I)-CATALYZED FORMATION; ACETYLENE DERIVATIVES; CATALYZED CYCLIZATION; ALPHA-HYDROXYALLENES; ALLENIC ALCOHOLS; RECENT PROGRESS; BIS-ALLENES;
D O I：
10.1002/adsc.200800469
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A stereoselective synthesis of conjugated bis(alpha-hydroxyallenes) by copper-mediated S(N)2'-substitution is described. Their silver- or gold-catalyzed cycloisomerization affords highly functionalized 2-allenyl-substituted 2,5-dihydrofurans and bis(2,5-dihydrofurans) under axis-to-center chirality transfer.
引用
收藏
页码：117 / 122
页数：6
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