Stereoselective Synthesis of Conjugated Bisallenols as Precursors of Novel Bis(2,5-dihydrofuran) Derivatives

被引：38

作者：

Poonoth, Manojkumar ^{[1
]}

Krause, Norbert ^{[1
]}

机构：

[1] Dortmund Univ Technol, D-44227 Dortmund, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 1-2期

关键词：

bisallenes; chirality transfer; cycloisomerization; gold catalysis; silver catalysis; ANNONACEOUS ACETOGENINS; GOLDEN OPPORTUNITIES; FUNCTIONALIZED 2,5-DIHYDROFURANS; GOLD(I)-CATALYZED FORMATION; ACETYLENE DERIVATIVES; CATALYZED CYCLIZATION; ALPHA-HYDROXYALLENES; ALLENIC ALCOHOLS; RECENT PROGRESS; BIS-ALLENES;

D O I：

10.1002/adsc.200800469

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A stereoselective synthesis of conjugated bis(alpha-hydroxyallenes) by copper-mediated S(N)2'-substitution is described. Their silver- or gold-catalyzed cycloisomerization affords highly functionalized 2-allenyl-substituted 2,5-dihydrofurans and bis(2,5-dihydrofurans) under axis-to-center chirality transfer.

引用

页码：117 / 122

页数：6

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