SYNTHESIS AND CHEMISTRY OF 2,5-DIMETHYLENE-2,5-DIHYDROFURAN

被引：11
|
作者：
CHEN, PS
CHOU, CH
机构：
[1] Department of Chemistry, National Sun Yat-Sen University, Kaohsiung
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1992年 / 39卷 / 03期
关键词：
2,5-DIMETHYLENE-2,5-DIHYDROFURAN; FLASH VACUUM PYROLYSIS;
D O I：
10.1002/jccs.199200043
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2,5-Dimethylene-2,5-dihydrofuran (3), generated flash pyrolitically, underwent di- and trimerization reactions to give cyclic dimer and trimer. Compound 3 was trapped with methanol, ethanol, bromine, acetic acid, thiophenol and oxygen. Results from trapping experiments suggest that the diradical form of 3 is involved.
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页码：251 / 255
页数：5
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