Synthesis and Structure of Heterodinuclear Rhodium and Iridium Borylene Complexes

被引：12
|
作者：
Braunschweig, Holger [1 ]
Forster, Melanie [1 ]
Seeler, Fabian [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 02期
关键词：
boron; borylene complexes; bridging ligands; iridium; rhodium; TRANSITION-METAL-COMPLEXES; REACTION CHEMISTRY; THERMAL CONDITIONS; BRIDGING LIGAND; BORON; COORDINATION; REACTIVITY; ABSTRACTION; MONONUCLEAR; BASE;
D O I：
10.1002/chem.200801820
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein we report on the synthesis and structural characterization of a representative range of novel heterodinuclear bridging rhodium and iridium borylene complexes. The iridium borylene complexes feature an unusual coordination mode of the borylene ligand. Furthermore, the first instance of a heterodinuclear-bridged borylene compound containing a chromium atom in the three-membered ring is reported.
引用
收藏
页码：469 / 473
页数：5
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