Surface-initiated reversible addition-fragmentation chain transfer polymerization from "clickable" polypropylene surface modified by iodine plasma activation

被引：7
|
作者：
Couturaud, B.
Mas, A.
Robin, Jean J. [1 ]
机构：
[1] CNRS, UMR 5253, Inst Charles Gerhardt, F-34095 Montpellier 5, France
来源：
EUROPEAN POLYMER JOURNAL | 2015年 / 70卷
关键词：
Surface; Iodine plasma; Activation; RAFT; Grafting; RADICAL POLYMERIZATION; SUBSTRATE; POLYETHYLENE; BRUSHES; DENSITY; HYBRIDS;
D O I：
10.1016/j.eurpolymj.2015.07.019
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An iodine modified polypropylene surface was synthesized by iodine plasma activation. The obtained polypropylene surface was found to be a useful platform for secondary reactions. For instance, an azide-functionalized PP was prepared by nucleophilic exchange reaction. The surface was proven to be reactive toward R group of an alkyne modified RAFT agent via the copper-catalyzed azide-alkyne cycloaddition. RAFT mediated graft polymerization of methacrylic acid was carried out and lead to a controlled polymerization from the surface. Characterizations of the modified surface and the grafted polymers were performed through FTIR-GATR, XPS, AFM and colorimetric assays. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：276 / 285
页数：10
相关论文
共 50 条
  • [41] Reversible addition-fragmentation chain transfer polymerization initiated with ultraviolet and gamma radiation: A comparison.
    Davis, TP
    Rizzardo, E
    Barner, L
    Barner-Kowollik, C
    Quinn, JF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U448 - U448
  • [42] Photoluminescent silicon nanocrystal-polymer hybrid materials via surface initiated reversible addition-fragmentation chain transfer (RAFT) polymerization
    Hoehlein, Ignaz M. D.
    Werz, Patrick D. L.
    Veinot, Jonathan G. C.
    Rieger, Bernhard
    NANOSCALE, 2015, 7 (17) : 7811 - 7818
  • [43] Hydrophilic modification of intraocular lens via surface initiated reversible addition-fragmentation chain transfer polymerization for reduced posterior capsular opacification
    Lin, Quankui
    Tang, Junmei
    Han, Yuemei
    Xu, Xu
    Hao, Xiaojuan
    Chen, Hao
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2017, 151 : 271 - 279
  • [44] Reversible Addition-fragmentation Chain Transfer Polymerization Grafted from Silicon Surface to Prepare Poly(methyl methacrylate) Brushes
    Yuan Kun
    Lue Ling-Ling
    Li Zhi-Feng
    Shi Xiao-Ning
    CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (10) : 1929 - 1934
  • [45] Controlled synthesis of water-compatible molecularly imprinted polymer microspheres with ultrathin hydrophilic polymer shells via surface-initiated reversible addition-fragmentation chain transfer polymerization
    Pan, Guoqing
    Ma, Yue
    Zhang, Ying
    Guo, Xianzhi
    Li, Chenxi
    Zhang, Huiqi
    SOFT MATTER, 2011, 7 (18) : 8428 - 8439
  • [46] Thermal-initiated reversible addition-fragmentation chain transfer polymerization of methyl methacrylate in the presence of oxygen
    Zhang, ZB
    Zhu, XL
    Zhu, J
    Cheng, ZP
    Zhu, SP
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (10) : 3343 - 3354
  • [47] Reversible addition-fragmentation chain-transfer polymerization of octadecyl acrylate
    Zhu, J
    Zhu, XL
    Cheng, ZP
    Lu, JM
    Liu, F
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2003, A40 (09): : 963 - 975
  • [48] Reversible addition-fragmentation chain transfer polymerization on different synthesizer platforms
    Paulus, RM
    Fijten, MWM
    de la Mar, MI
    Hoogenboom, R
    Schubert, US
    QSAR & COMBINATORIAL SCIENCE, 2005, 24 (07): : 863 - 867
  • [49] 'Green' reversible addition-fragmentation chain-transfer (RAFT) polymerization
    Semsarilar, Mona
    Perrier, Sebastien
    NATURE CHEMISTRY, 2010, 2 (10) : 811 - 820
  • [50] Reversible addition-fragmentation chain transfer polymerization of methyl methacrylate in emulsion
    Luo, YW
    Cui, XF
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (09) : 2837 - 2847
12345