Synthesis of four new carboxylic derivatives based on the [1.1.1.1]metacyclophane backbone blocked in 1,3-Alternate conformation

被引：4

作者：

Chernova, Ekaterina F. ^{[1
,2
]}

Ovsyannikov, Alexander S. ^{[2
,3
]}

Ferlay, Sylvie ^{[1
]}

Solovieva, Svetlana E. ^{[2
,3
]}

Antipin, Igor S. ^{[2
,3
]}

Konovalov, Alexander I. ^{[2
,3
]}

Kyritsakas, Nathalie ^{[1
]}

Hosseini, Mir Wais ^{[1
]}

机构：

[1] Univ Strasbourg, Mol Tecton Lab, UMR UDS CNRS 7140, Inst le Bel, 4 Rue Blaise Pascal, F-67000 Strasbourg, France

[2] Kazan Fed Univ, Kremlevskaya Str 18, Kazan 420008, Russia

[3] Russian Acad Sci, AE Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Arbuzov Str 8, Kazan 420008, Russia

来源：

TETRAHEDRON LETTERS | 2018年 / 59卷 / 14期

基金：

俄罗斯基础研究基金会;

关键词：

Carboxylate ligand; 1,3-Alternate conformation; Metacyclophane backbone; Ester derivatives; Suzuki coupling; STRUCTURAL-ANALYSIS; MOLECULAR TECTONICS; COORDINATION; METAL; COMPLEXATION; ALKALI; DESIGN;

D O I：

10.1016/j.tetlet.2018.02.060

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Four new tetrasubstituted [1.1.1.1]metacyclophanes (4-7), that are inherently adopting a 1,3-Alternate conformation, bearing four or eight peripheral carboxylic binding sites, and appended with spacers group (alkyl or phenyl) differing by the flexibility, have been synthesised in high yields. The structures of the obtained compounds have been investigated in solution as well as in the solid state, for three of them, by using single-crystal X-ray analysis. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：1377 / 1381

页数：5

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