Preparation and characterization of porous polymeric microspheres obtained from multifunctional methacrylate monomers

被引：19

作者：

Grochowicz, Marta ^{[1
]}

Bartnicki, Andrzej ^{[1
]}

Gawdzik, Barbara ^{[1
]}

机构：

[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 18期

关键词：

2-hydroxy-3-methacryloyloxypropoxybenzene; macroporous polymers; monomers; polymeric microspheres; suspension-emulsion copolymerization; swelling;

D O I：

10.1002/pola.22927

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Synthesis and properties of the new difunctional methacrylate monomer 2-hydroxy-3-methacryloyloxypropoxybenzene are presented. This monomer was applied for the synthesis of porous microspheres. It was copolymerized with trimethylolpropane trimethacrylate in the presence of two pairs of pore-forming diluents dodecane and toluene, and n-decanol and toluene. Influence of diluents composition on their porous structures was studied. Thermal resistance and tendency to swell in different organic diluents for a chosen sample were also determined. (C) 2008 Wiley Periodicals, Inc.

引用

页码：6165 / 6174

页数：10

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