Preparation and characterization of porous polymeric microspheres obtained from multifunctional methacrylate monomers

被引：19
|
作者：
Grochowicz, Marta [1 ]
Bartnicki, Andrzej [1 ]
Gawdzik, Barbara [1 ]
机构：
[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 18期
关键词：
2-hydroxy-3-methacryloyloxypropoxybenzene; macroporous polymers; monomers; polymeric microspheres; suspension-emulsion copolymerization; swelling;
D O I：
10.1002/pola.22927
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Synthesis and properties of the new difunctional methacrylate monomer 2-hydroxy-3-methacryloyloxypropoxybenzene are presented. This monomer was applied for the synthesis of porous microspheres. It was copolymerized with trimethylolpropane trimethacrylate in the presence of two pairs of pore-forming diluents dodecane and toluene, and n-decanol and toluene. Influence of diluents composition on their porous structures was studied. Thermal resistance and tendency to swell in different organic diluents for a chosen sample were also determined. (C) 2008 Wiley Periodicals, Inc.
引用
收藏
页码：6165 / 6174
页数：10
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