Energetic cuprous azide complex: synthesis, crystal structure, and characterization

被引：7

作者：

Guang, Fan ^{[1
]}

Yin-Li, Zhang ^{[1
]}

Jia-Juan, Sun ^{[1
]}

Min-Yan, Zheng ^{[1
]}

机构：

[1] Xianyang Normal Univ, Coll Chem & Chem Engn, Xianyang 712000, Shaanxi, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 21期

关键词：

Energetic complex; Cuprous azide; Crystal structure; Catalysis action; BINUCLEAR CU(II) COMPLEX; COMPOUND; MAGNETISM;

D O I：

10.1080/00958972.2011.629656

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An energetic cuprous azide complex, [Cu-2(2apyz)(N-3)(2)](n) (1) (2apyz = 2-aminopyrazine), has been synthesized through hydrothermal method by utilizing the reducibility of H3PO3 and structurally characterized by single-crystal X-ray diffraction. Complex 1 has a 2-D layer structure constructed from copper(I) bridged by azide and pyrazine. Catalysis research shows 1 can promote the burning rate of the main component of rocket propellant.

引用

页码：3711 / 3717

页数：7

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