Energetic cuprous azide complex: synthesis, crystal structure, and characterization

被引：7
|
作者：
Guang, Fan [1 ]
Yin-Li, Zhang [1 ]
Jia-Juan, Sun [1 ]
Min-Yan, Zheng [1 ]
机构：
[1] Xianyang Normal Univ, Coll Chem & Chem Engn, Xianyang 712000, Shaanxi, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 21期
关键词：
Energetic complex; Cuprous azide; Crystal structure; Catalysis action; BINUCLEAR CU(II) COMPLEX; COMPOUND; MAGNETISM;
D O I：
10.1080/00958972.2011.629656
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An energetic cuprous azide complex, [Cu-2(2apyz)(N-3)(2)](n) (1) (2apyz = 2-aminopyrazine), has been synthesized through hydrothermal method by utilizing the reducibility of H3PO3 and structurally characterized by single-crystal X-ray diffraction. Complex 1 has a 2-D layer structure constructed from copper(I) bridged by azide and pyrazine. Catalysis research shows 1 can promote the burning rate of the main component of rocket propellant.
引用
收藏
页码：3711 / 3717
页数：7
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